Journal

Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951

Informations de publication

Date de publication:
21 Apr 2019
Historique:
received: 22 11 2018
accepted: 08 03 2019
entrez: 7 5 2019
pubmed: 7 5 2019
medline: 7 5 2019
Statut: epublish

Résumé

Most developments in the chemistry and applications of metal-organic frameworks (MOFs) have been made possible thanks to the value of reticular chemistry in guiding the unlimited combination of organic connectors and secondary building units (SBUs) into targeted architectures. However, the development of new titanium-frameworks still remains limited by the difficulties in controlling the formation of persistent Ti-SBUs with predetermined directionality amenable to the isoreticular approach. Here we report the synthesis of a mesoporous Ti-MOF displaying a MIL-100 topology. MIL-100(Ti) combines excellent chemical stability and mesoporosity, intrinsic to this archetypical family of porous materials, with photoactive Ti

Identifiants

pubmed: 31057758
doi: 10.1039/c8sc05218b
pii: c8sc05218b
pmc: PMC6472189
doi:

Types de publication

Journal Article

Langues

eng

Pagination

4313-4321

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Auteurs

Javier Castells-Gil (J)

Universidad de Valencia (ICMol) , Catedrático José Beltrán-2 , 46980 , Paterna , Spain . Email: carlos.marti@uv.es.

Natalia M Padial (N)

Universidad de Valencia (ICMol) , Catedrático José Beltrán-2 , 46980 , Paterna , Spain . Email: carlos.marti@uv.es.
Department of Chemistry , The Scripps Research Institute , 10550 North Torrey Pines Road , La Jolla , California 92037 , USA.

Neyvis Almora-Barrios (N)

Universidad de Valencia (ICMol) , Catedrático José Beltrán-2 , 46980 , Paterna , Spain . Email: carlos.marti@uv.es.

Ivan da Silva (I)

ISIS Facility , Rutherford Appleton Laboratory , Chilton , Didcot , Oxfordshire OX11 0QX , UK.

Diego Mateo (D)

Instituto Universitario de Tecnología Química CSIC-UPV , Universitat Politècnica de València , Av. De Los Naranjos s/n , 46022 , Valencia , Spain.

Josep Albero (J)

Instituto Universitario de Tecnología Química CSIC-UPV , Universitat Politècnica de València , Av. De Los Naranjos s/n , 46022 , Valencia , Spain.

Hermenegildo García (H)

Instituto Universitario de Tecnología Química CSIC-UPV , Universitat Politècnica de València , Av. De Los Naranjos s/n , 46022 , Valencia , Spain.

Carlos Martí-Gastaldo (C)

Universidad de Valencia (ICMol) , Catedrático José Beltrán-2 , 46980 , Paterna , Spain . Email: carlos.marti@uv.es.

Classifications MeSH