Highly stable fullerene-based porous molecular crystals with open metal sites.


Journal

Nature materials
ISSN: 1476-4660
Titre abrégé: Nat Mater
Pays: England
ID NLM: 101155473

Informations de publication

Date de publication:
07 2019
Historique:
received: 20 07 2018
accepted: 29 03 2019
pubmed: 16 5 2019
medline: 16 5 2019
entrez: 16 5 2019
Statut: ppublish

Résumé

The synthesis of conventional porous crystals involves building a framework using reversible chemical bond formation, which can result in hydrolytic instability. In contrast, porous molecular crystals assemble using only weak intermolecular interactions, which generally do not provide the same environmental stability. Here, we report that the simple co-crystallization of a phthalocyanine derivative and a fullerene (C

Identifiants

pubmed: 31086318
doi: 10.1038/s41563-019-0361-0
pii: 10.1038/s41563-019-0361-0
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Pagination

740-745

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Auteurs

C Grazia Bezzu (CG)

EaStCHEM, School of Chemistry, University of Edinburgh, Edinburgh, UK.

Luke A Burt (LA)

EaStCHEM, School of Chemistry, University of Edinburgh, Edinburgh, UK.

Charlie J McMonagle (CJ)

EaStCHEM, School of Chemistry, University of Edinburgh, Edinburgh, UK.

Stephen A Moggach (SA)

EaStCHEM, School of Chemistry, University of Edinburgh, Edinburgh, UK.
Centre for Microscopy, Characterisation and Analysis and School of Molecular Sciences, The University of Western Australia (M310), Perth, Western Australia, Australia.

Benson M Kariuki (BM)

School of Chemistry, Cardiff University, Cardiff, UK.

David R Allan (DR)

Diamond Light Source, Didcot, UK.

Mark Warren (M)

Diamond Light Source, Didcot, UK.

Neil B McKeown (NB)

EaStCHEM, School of Chemistry, University of Edinburgh, Edinburgh, UK. neil.mckeown@ed.ac.uk.

Classifications MeSH