Organic Redox Systems Based on Pyridinium-Carbene Hybrids.

New redox systems with three oxidation states are highly sought-after, for example, for redox-flow battery applications, selective reducing agents, or organic electronics. Herein, we describe a straightforward and modular synthesis of a new class of such a three-state redox system based on the intermolecular reaction of a large variety of pyridinium salts with carbenes. These hybrids represent organic (super) electron donors with tailored electrochemical properties and feature three stable oxidation states, which could be fully characterized including by X-ray diffraction. We elaborate which electronic factors either promote attainment of stable radicals through one electron transfer or instead favor 2e