Simultaneous determination of parabens, bisphenols and alkylphenols in human placenta by ultra-high performance liquid chromatography-tandem mass spectrometry.


Journal

Journal of chromatography. B, Analytical technologies in the biomedical and life sciences
ISSN: 1873-376X
Titre abrégé: J Chromatogr B Analyt Technol Biomed Life Sci
Pays: Netherlands
ID NLM: 101139554

Informations de publication

Date de publication:
15 Jul 2019
Historique:
received: 22 06 2018
revised: 07 05 2019
accepted: 12 05 2019
pubmed: 29 5 2019
medline: 21 8 2019
entrez: 29 5 2019
Statut: ppublish

Résumé

This study presents de development and validation of an ultra- high performance liquid chromatography - tandem mass spectrometry (UHPLC-MS/MS) method for the simultaneous determination of four parabens (methyl-, ethyl-, propyl-, and butyl-paraben (MeP, EtP, PrP, BuP), four bisphenols (BP) (BPA, BPB, BPF, and BPS) and two alkylphenols (nonyl phenol (NP) and tert-octylphenol (OP) in human placenta samples. After a short sample preparation time the extracts are analysed by UHPLC-MS/MS using negative electrospray ionization. Labeled internal standards and matrix-matched calibration are used for quantification of the compounds. The method was validated according FDA guideline for bio analytical methods using spiked samples at three concentration levels (0.5-5 and 25 ng g

Identifiants

pubmed: 31136871
pii: S1570-0232(18)30962-0
doi: 10.1016/j.jchromb.2019.05.012
pii:
doi:

Substances chimiques

Parabens 0
Phenols 0

Types de publication

Journal Article

Langues

eng

Pagination

96-102

Informations de copyright

Copyright © 2019 Elsevier B.V. All rights reserved.

Auteurs

Ilse Van Overmeire (I)

Sciensano, Chemical and physical health risks, 1050 Brussels, Belgium. Electronic address: Ilse.vanovermeire@sciensano.be.

Karen Vrijens (K)

Center for Environmental Sciences, Hasselt University, 3500 Hasselt, Belgium.

Tim Nawrot (T)

Center for Environmental Sciences, Hasselt University, 3500 Hasselt, Belgium; Department of Public Health, Environment & Health Unit, Leuven University (KU Leuven), 3000 Leuven, Belgium.

An Van Nieuwenhuyse (A)

Sciensano, Chemical and physical health risks, 1050 Brussels, Belgium.

Joris Van Loco (J)

Sciensano, Chemical and physical health risks, 1050 Brussels, Belgium.

Tim Reyns (T)

Sciensano, Chemical and physical health risks, 1050 Brussels, Belgium.

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Classifications MeSH