Ligand-Directed Template Assembly for the Construction of Gigantic Molybdenum Blue Wheels.
anion templation
gigantic cluster
host-guest chemistry
molybdenum blue
polyoxometalates
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
05 Aug 2019
05 Aug 2019
Historique:
received:
11
02
2019
revised:
25
04
2019
pubmed:
4
6
2019
medline:
4
6
2019
entrez:
4
6
2019
Statut:
ppublish
Résumé
Template-mediated synthesis is a powerful approach to build a variety of functional materials and complex supramolecular systems. However, the systematic study of how templates structurally evolve from basic building blocks, and then affect the templated self-assembly, is critical to understanding and utilizing the underlying mechanism, to work towards designed assembly. Here we describe the templated self-assembly of a series of gigantic Mo Blue (MB) clusters 1-4 using l-ornithine as a structure-directing ligand. We show that by using l-ornithine as a structure director, we can form new template⊂host assemblies. Based on the structural relationship between encapsulated templates of {Mo
Identifiants
pubmed: 31155800
doi: 10.1002/anie.201901818
pmc: PMC6771582
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
10867-10872Subventions
Organisme : Engineering and Physical Sciences Research Council
ID : EP/J015156/1; EP/L023652/1; EP/I033459/1; EP/J015156/1; EP/K023004/1; EP/L023652/1
Organisme : H2020 European Research Council
ID : 670467 SMART-POM
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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