Silicon-Mediated Coupling of Carbon Monoxide, Ammonia, and Primary Amines to Form Acetamides.
ammonolysis
carbonylamination
carbonylation
disilaketene
silylenes
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
09 Sep 2019
09 Sep 2019
Historique:
received:
09
04
2019
revised:
27
05
2019
pubmed:
4
6
2019
medline:
4
6
2019
entrez:
4
6
2019
Statut:
ppublish
Résumé
For the first time, a direct transformation of CO, NH
Identifiants
pubmed: 31157488
doi: 10.1002/anie.201904361
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
12940-12944Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : Cluster of Excellence UniSysCat
Organisme : Alexander von Humboldt-Stiftung
Organisme : Einstein Stiftung Berlin
ID : Einstein Visiting Grant
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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The geometries were optimized at B3LYP-D3 using the s6-31G* basis set for iron and def2-SVP for all other atoms. The tBu and Ph groups of the amidinato substituents were replaced by methyl groups. For details, see the Supporting Information.
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