Oxidative Coupling of Terminal Rhenium Pnictide Complexes.
QTAIM
dipnictides
pincer complexes
pnictides
rhenium
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
05 Aug 2019
05 Aug 2019
Historique:
received:
24
04
2019
revised:
27
05
2019
pubmed:
11
6
2019
medline:
11
6
2019
entrez:
11
6
2019
Statut:
ppublish
Résumé
The isolation of rhenium(V) complexes with terminal phosphide and arsenide ligands was achieved upon decarbonylation of rhenium(III) pnictaethynolates. One-electron oxidation of the pnictide complexes yielded Pn-Pn (Pn=P, As) coupling products, which were spectroscopically and crystallographically characterized. Computational bond analysis suggests that these complexes are best described as {Pn
Identifiants
pubmed: 31179626
doi: 10.1002/anie.201905130
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
10966-10970Subventions
Organisme : European Research Council
ID : CoG 646747
Pays : International
Organisme : Fonds der Chemischen Industrie
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.