2-Cyano-2-phenylpropanoic Acid Triggers the Back and Forth Motions of an Acid-Base-Operated Paramagnetic Molecular Switch.
Journal
The Journal of organic chemistry
ISSN: 1520-6904
Titre abrégé: J Org Chem
Pays: United States
ID NLM: 2985193R
Informations de publication
Date de publication:
19 07 2019
19 07 2019
Historique:
pubmed:
18
6
2019
medline:
18
6
2019
entrez:
18
6
2019
Statut:
ppublish
Résumé
The back and forth motions of a crown-ether based wheel along the axis of a bistable rotaxane are triggered by the decarboxylation of 2-cyano-2-phenylpropanoic acid and detected by the oscillation of the EPR nitrogen splitting of a dialkyl nitroxide function mounted within the macrocyclic ring. When the
Identifiants
pubmed: 31203619
doi: 10.1021/acs.joc.9b01164
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM