Phase Rule and the Universality of Critical Phenomena in Chemically Reacting Liquid Mixtures.

Critical effects have been reported in the case of chemical equilibria, in which the solvent is a binary liquid mixture having a critical point of solution. At atmospheric pressure and for temperatures near the critical point, the critical effect manifests itself as a divergence in the temperature derivative of the extent of reaction. For a critical mixture of isobutyric acid + water (IBA/H