Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones.
Journal
Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393
Informations de publication
Date de publication:
05 Jul 2019
05 Jul 2019
Historique:
pubmed:
30
6
2019
medline:
30
6
2019
entrez:
29
6
2019
Statut:
ppublish
Résumé
The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates scope. The resulting crude organotin derivatives can be directly employed in a Stille protocol.
Identifiants
pubmed: 31247810
doi: 10.1021/acs.orglett.9b01788
doi:
Types de publication
Journal Article
Langues
eng