Stereoselective Alkyne Hydrogenation by using a Simple Iron Catalyst.
alkynes
hydrogenation
iron
nanoparticles
stereoselectivity
Journal
ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536
Informations de publication
Date de publication:
22 Aug 2019
22 Aug 2019
Historique:
received:
04
04
2019
revised:
04
06
2019
pubmed:
3
7
2019
medline:
3
7
2019
entrez:
3
7
2019
Statut:
ppublish
Résumé
The stereoselective hydrogenation of alkynes constitutes one of the key approaches for the construction of stereodefined alkenes. The majority of conventional methods utilize noble and toxic metal catalysts. This study concerns a simple catalyst comprised of the commercial chemicals iron(II) acetylacetonate and diisobutylaluminum hydride, which enables the Z-selective semihydrogenation of alkynes under near ambient conditions (1-3 bar H
Identifiants
pubmed: 31265757
doi: 10.1002/cssc.201900926
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3864-3870Subventions
Organisme : Deutsche Forschungsgemeinschaft
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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