A glassy carbon electrode modified with silver nanoparticles and functionalized multi-walled carbon nanotubes for voltammetric determination of the illicit growth promoter dienestrol in animal urine.


Journal

Mikrochimica acta
ISSN: 1436-5073
Titre abrégé: Mikrochim Acta
Pays: Austria
ID NLM: 7808782

Informations de publication

Date de publication:
10 07 2019
Historique:
received: 13 02 2019
accepted: 27 06 2019
entrez: 12 7 2019
pubmed: 12 7 2019
medline: 17 4 2020
Statut: epublish

Résumé

An electroanalytical method for determining dienestrol (DNL) in bovine urine samples is described. A glassy carbon electrode (GCE) modified with silver nanoparticles and functionalized multi-walled carbon nanotubes was used as working sensor. The modified GCE displays substantial analytical improvements including an amplified signal, fast electron transfer kinetics, and resistance to fouling. The irreversible oxidation signal of DNL is pH-dependent. Best reactivity is found at pH 3.0, where a typical anodic peak is recorded at 0.8 V (vs. Ag/AgCl). Square-wave voltammetry revealed a 8.4 nM detection limit (1.9 μg L

Identifiants

pubmed: 31292777
doi: 10.1007/s00604-019-3645-9
pii: 10.1007/s00604-019-3645-9
doi:

Substances chimiques

Illicit Drugs 0
Nanotubes, Carbon 0
Silver 3M4G523W1G
Dienestrol RRW32X4U1F

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

525

Subventions

Organisme : Coordination for the Improvement of Higher Education Personnel (BR)
ID : 88881.140821/2017-01
Pays : International
Organisme : Coordination for the Improvement of Higher Education Personnel
ID : Finance code 001
Pays : International
Organisme : National Council for Scientific and Technological Development (BR)
ID : 420261/2018-4
Pays : International
Organisme : National Council for Scientific and Technological Development (BR)
ID : 407891/2018-8
Pays : International

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Auteurs

Manoel M S Lima Filho (MMS)

Faculdade de Química, Instituto de Ciências Exatas, Universidade Federal do Sul e Sudeste do Pará, Folha 17, Quadra 04, Lote Especial, Marabá, PA, 68505-080, Brazil.

Alessandra A Correa (AA)

Departamento de Química, Universidade Federal de São Carlos, Rodovia Washington Luis, CP 676, São Carlos, SP, 13565-905, Brazil.

Francisco D C Silva (FDC)

Centro de Ciência e Tecnologia, Universidade Federal do Cariri, Rua Tenente Raimundo Rocha, 1639, Cidade Universitária, Juazeiro do Norte, CE, 63048-080, Brazil.

Francisco A O Carvalho (FAO)

Faculdade de Química, Instituto de Ciências Exatas, Universidade Federal do Sul e Sudeste do Pará, Folha 17, Quadra 04, Lote Especial, Marabá, PA, 68505-080, Brazil.

Lúcia H Mascaro (LH)

Departamento de Química, Universidade Federal de São Carlos, Rodovia Washington Luis, CP 676, São Carlos, SP, 13565-905, Brazil.

Thiago M B F Oliveira (TMBF)

Centro de Ciência e Tecnologia, Universidade Federal do Cariri, Rua Tenente Raimundo Rocha, 1639, Cidade Universitária, Juazeiro do Norte, CE, 63048-080, Brazil. thiago.mielle@ufca.edu.br.

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