Non-conventional mechanism of ferroelectric fatigue via cation migration.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
11 Jul 2019
Historique:
received: 12 11 2018
accepted: 21 06 2019
entrez: 13 7 2019
pubmed: 13 7 2019
medline: 13 7 2019
Statut: epublish

Résumé

The unique properties of ferroelectric materials enable a plethora of applications, which are hindered by the phenomenon known as ferroelectric fatigue that leads to the degradation of ferroelectric properties with polarization cycling. Multiple microscopic models explaining fatigue have been suggested; however, the chemical origins remain poorly understood. Here, we utilize multimodal chemical imaging that combines atomic force microscopy with time-of-flight secondary mass spectrometry to explore the chemical phenomena associated with fatigue in PbZr

Identifiants

pubmed: 31296880
doi: 10.1038/s41467-019-11089-w
pii: 10.1038/s41467-019-11089-w
pmc: PMC6624312
doi:

Types de publication

Journal Article

Langues

eng

Pagination

3064

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Auteurs

Anton V Ievlev (AV)

The Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA. ievlevav@ornl.gov.

Santosh Kc (S)

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.

Rama K Vasudevan (RK)

The Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.

Yunseok Kim (Y)

School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, 16419, Republic of Korea.

Xiaoli Lu (X)

The State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, Xidian University, 710071, Xi'an, China.

Marin Alexe (M)

Department of Physics, University of Warwick, Coventry, CV4 7AL, UK.

Valentino R Cooper (VR)

Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.

Sergei V Kalinin (SV)

The Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.

Olga S Ovchinnikova (OS)

The Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA. ovchinnikovo@ornl.gov.

Classifications MeSH