Monitoring the Formation and Reactivity of Organometallic Alkane and Fluoroalkane Complexes with Silanes and Xe Using Time-Resolved X-ray Absorption Fine Structure Spectroscopy.

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
24 Jul 2019
Historique:
pubmed: 16 7 2019
medline: 16 7 2019
entrez: 16 7 2019
Statut: ppublish

Résumé

Complexes with weakly coordinating ligands are often formed in chemical reactions and can play key roles in determining the reactivity, particularly in catalytic reactions. Using time-resolved X-ray absorption fine structure (XAFS) spectroscopy in combination with time-resolved IR (TRIR) spectroscopy and tungsten hexacarbonyl, W(CO)

Identifiants

DOI: 10.1021/jacs.8b13848 PMID: 31306004
pubmed: 31306004
doi: 10.1021/jacs.8b13848
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

11471-11480

Auteurs

Stuart A Bartlett (SA)

DySS, Research Complex at Harwell , Rutherford Appleton Laboratory , Didcot OX11 0FA , U.K.
School of Chemistry , The University of Sydney , Eastern Avenue , Sydney , NSW 2006 , Australia.
Department of Chemistry , University of Bath , Claverton Down , Bath BA2 7AY , U.K.

Nicholas A Besley (NA)

School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.
ORCID: 0000-0003-1011-6675

Andrew J Dent (AJ)

Diamond Light Source , Harwell Science and Innovation Campus , Didcot , Oxfordshire OX11 0DE , U.K.

Sofia Diaz-Moreno (S)

Diamond Light Source , Harwell Science and Innovation Campus , Didcot , Oxfordshire OX11 0DE , U.K.

John Evans (J)

DySS, Research Complex at Harwell , Rutherford Appleton Laboratory , Didcot OX11 0FA , U.K.
Diamond Light Source , Harwell Science and Innovation Campus , Didcot , Oxfordshire OX11 0DE , U.K.
Chemistry , University of Southampton , Southampton SO17 1BJ , U.K.

Michelle L Hamilton (ML)

DySS, Research Complex at Harwell , Rutherford Appleton Laboratory , Didcot OX11 0FA , U.K.
School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.

Magnus W D Hanson-Heine (MWD)

School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.
ORCID: 0000-0002-6709-297X

Raphael Horvath (R)

School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.

Valentina Manici (V)

DySS, Research Complex at Harwell , Rutherford Appleton Laboratory , Didcot OX11 0FA , U.K.
School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.

Xue-Zhong Sun (XZ)

School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.

Michael Towrie (M)

DySS, Research Complex at Harwell , Rutherford Appleton Laboratory , Didcot OX11 0FA , U.K.
Central Laser Facility, Research Complex at Harwell , Rutherford Appleton Laboratory , Chilton , Oxfordshire OX11 0QX , U.K.

Lingjun Wu (L)

School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.

Xiaoyi Zhang (X)

X-ray Science Division , Argonne National Laboratory , Lemont , Illinois 60439 , United States.
ORCID: 0000-0001-9732-1449

Michael W George (MW)

DySS, Research Complex at Harwell , Rutherford Appleton Laboratory , Didcot OX11 0FA , U.K.
School of Chemistry , University of Nottingham , University Park NG7 2RD , U.K.
Department of Chemical and Environmental Engineering , University of Nottingham Ningbo China , 199 Taikang East Road , Ningbo 315100 , China.
ORCID: 0000-0002-7844-1696

Classifications MeSH