Gold(I) Complexes Stabilized by Nine- and Ten-Membered N-Heterocyclic Carbene Ligands.
N-heterocyclic carbenes
carbenes
catalysis
gold
ligands
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
06 Sep 2019
06 Sep 2019
Historique:
received:
29
05
2019
pubmed:
17
7
2019
medline:
17
7
2019
entrez:
17
7
2019
Statut:
ppublish
Résumé
Nine- and ten-membered N-heterocyclic carbene (NHC) ligands have been developed and for the first time their gold(I) complexes were synthesized. The protonated NHC pro-ligands 2 a-h were prepared by the reaction of readily available N,N'-diarylformamidines with bis-electrophilic building blocks, followed by anion exchange. In situ deprotonation of the tetrafluoroborates 2 a-h with tBuOK in the presence of AuCl(SMe
Identifiants
pubmed: 31310385
doi: 10.1002/chem.201902458
pmc: PMC6852534
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
11745-11757Subventions
Organisme : Consejo Nacional de Ciencia y Tecnología
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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