Ligand Effect in Alkali-Metal-Catalyzed Transfer Hydrogenation of Ketones.
DFT calculation
catalysis
ligands
lithium
transfer hydrogenation
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
06 Sep 2019
06 Sep 2019
Historique:
received:
15
05
2019
pubmed:
19
7
2019
medline:
19
7
2019
entrez:
19
7
2019
Statut:
ppublish
Résumé
This work unveils the reactivity patterns, as well as ligand and additive effect on alkali-metal-base-catalyzed transfer hydrogenation of ketones. Crucially to this reactivity is the presence of a Lewis acid (alkali cation), as opposed to a simple base effect. With aryl ketones, the observed reactivity order is Na
Identifiants
pubmed: 31318992
doi: 10.1002/chem.201902240
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
11734-11744Subventions
Organisme : NSERC
ID : 2017-05231
Organisme : NSERC
ID : 2012-326899
Organisme : NSERC
ID : 2014-04410
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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