Spontaneous Complexation of Fullerene Aggregates on Nanodiamond Aggregates and Their Enhanced Photocurrent Generation.
Electron transfer
Electrophoretic deposition
Fullerenes
Nanodiamond
Photoelectrochemistry
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
18 Nov 2019
18 Nov 2019
Historique:
received:
19
06
2019
pubmed:
25
7
2019
medline:
25
7
2019
entrez:
24
7
2019
Statut:
ppublish
Résumé
Supramolecular composites composed of fullerene C
Identifiants
pubmed: 31334595
doi: 10.1002/asia.201900835
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4042-4047Subventions
Organisme : Japan Society for the Promotion of Science
ID : JP18H03898
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Because the sizes of π-conjugation on the sp2 carbon shells of ND are non-uniform, each ND particle has various one-electron oxidation potentials. Nevertheless, we estimated the average oxidation potential of ND to be 1.9 V vs. NHE by the photoemission yield spectroscopy in air (PYSA) method (Figure S8), which matches well with the reported value (1.8 V vs. NHE) (ref. 20). In addition, ND showed ambiguous absorption edge (Figures 2 and S3) and no emission, which complicated the estimation of the optical band gap of ND. Therefore, we took the value of ND band gap (2.5 eV) from the literature (ref. 21).
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