Pd/NHC-catalyzed cross-coupling reactions of nitroarenes.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
14 Aug 2019
14 Aug 2019
Historique:
pubmed:
25
7
2019
medline:
25
7
2019
entrez:
25
7
2019
Statut:
ppublish
Résumé
N-Heterocyclic carbene (NHC) ligands effective for the cross-coupling of nitroarenes were identified. A rational design of the NHC ligand structures enabled significant reduction of catalyst loadings compared with the previous system employing BrettPhos as a phosphine ligand. Experimental and theoretical studies to compare these ligands gave some insights into high activity of the newly developed NHC ligands.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM