Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks.
conductivity
lanthanide
luminescence
metal-organic framework
single-molecule magnet
tetrathiafulvalene
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
25 Sep 2019
25 Sep 2019
Historique:
received:
21
06
2019
pubmed:
28
7
2019
medline:
28
7
2019
entrez:
28
7
2019
Statut:
ppublish
Résumé
Tetrathiafulvalene-lanthanide (TTF-Ln) metal-organic frameworks (MOFs) are an interesting class of multifunctional materials in which porosity can be combined with electronic properties such as electrical conductivity, redox activity, luminescence and magnetism. Herein a new family of isostructural TTF-Ln MOFs is reported, denoted as MUV-5(Ln) (Ln=Gd, Tb, Dy, Ho, Er), exhibiting semiconducting properties as a consequence of the short intermolecular S⋅⋅⋅S contacts established along the chain direction between partially oxidised TTF moieties. In addition, this family shows photoluminescence properties and single-molecule magnetic behaviour, finding near-infrared (NIR) photoluminescence in the Yb/Er derivative and slow relaxation of the magnetisation in the Dy and Er derivatives. As such properties are dependent on the electronic structure of the lanthanide ion, the immense structural, electronic and functional versatility of this class of materials is emphasised.
Identifiants
pubmed: 31350922
doi: 10.1002/chem.201902855
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
12636-12643Subventions
Organisme : H2020 European Research Council
ID : 724681
Organisme : Ministry of Science, Innovation and Universities
ID : CTQ2017-89528-P
Organisme : Ministry of Science, Innovation and Universities
ID : MAT2017-89993-R
Organisme : Ministry of Science, Innovation and Universities
ID : MDM-2015-0538
Organisme : Centro de Investigação em Materiais Cerâmicos e Compósitos
ID : UID/CTM/50011/2019
Organisme : Generalitat Valenciana
ID : PROMETEO/2017/066
Organisme : H2020 Marie Skłodowska-Curie Actions
ID : H2020-MSCA-IF-2016-751047
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Références
G. Maurin, C. Serre, A. Cooper, G. Férey, Chem. Soc. Rev. 2017, 46, 3104-3107.
L. Sun, M. G. Campbell, M. Dincǎ, Angew. Chem. Int. Ed. 2016, 55, 3566-3579;
Angew. Chem. 2016, 128, 3628-3642.
I. Stassen, N. Burtch, A. Talin, P. Falcaro, M. Allendorf, R. Ameloot, Chem. Soc. Rev. 2017, 46, 3185-3241.
G. Mínguez Espallargas, E. Coronado, Chem. Soc. Rev. 2018, 47, 533-557.
J. Rocha, L. D. Carlos, F. A. A. Paz, D. Ananias, Chem. Soc. Rev. 2011, 40, 926-940.
W. P. Lustig, S. Mukherjee, N. D. Rudd, A. V. Desai, J. Li, S. K. Ghosh, Chem. Soc. Rev. 2017, 46, 3242-3285.
B. Li, H. M. Wen, Y. Cui, W. Zhou, G. Qian, B. Chen, Adv. Mater. 2016, 28, 8819-8860.
H.-Y. Wang, L. Cui, J.-Z. Xie, C. F. Leong, D. M. D′Alessandro, J.-L. Zuo, Coord. Chem. Rev. 2017, 345, 342-361.
T. C. Narayan, T. Miyakai, S. Seki, M. Dincǎ, J. Am. Chem. Soc. 2012, 134, 12932-12935.
S. S. Park, E. R. Hontz, L. Sun, C. H. Hendon, A. Walsh, T. Van Voorhis, M. Dincǎ, J. Am. Chem. Soc. 2015, 137, 1774-1777.
H.-Y. Wang, J.-Y. Ge, C. Hua, C.-Q. Jiao, Y. Wu, C. F. Leong, D. M. D′Alessandro, T. Liu, J.-L. Zuo, Angew. Chem. Int. Ed. 2017, 56, 5465-5470;
Angew. Chem. 2017, 129, 5557-5562.
M. Souto, A. Santiago-Portillo, M. Palomino, I. J. Vitórica-Yrezábal, B. J. C. Vieira, J. C. Waerenborgh, S. Valencia, S. Navalón, F. Rey, H. García, G. Mínguez Espallargas, Chem. Sci. 2018, 9, 2413-2418.
J. Su, S. Yuan, H.-Y. Wang, L. Huang, J.-Y. Ge, E. Joseph, J. Qin, T. Cagin, J.-L. Zuo, H.-C. Zhou, Nat. Commun. 2017, 8, 2008.
M. Souto, J. Romero, J. Calbo, I. J. Vitorica-Yrezabal, J. L. Zafra, J. Casado, E. Ortí, A. Walsh, G. Mínguez Espallargas, J. Am. Chem. Soc. 2018, 140, 10562-10569.
D. M. P. Mingos, Lanthanide Metal-Organic Frameworks, Springer, Heidelberg, 2015.
J. J. Baldoví, E. Coronado, A. Gaita-Ariño, C. Gamer, M. Giménez-Marqués, G. Mínguez Espallargas, Chem. Eur. J. 2014, 20, 10695-10702.
J. Castells-Gil, J. J. Baldoví, C. Martí-Gastaldo, G. Mínguez Espallargas, Dalton Trans. 2018, 47, 14734-14740.
A. Gaita-Ariño, F. Luis, S. Hill, E. Coronado, Nat. Chem. 2019, 11, 301-309.
F. Pointillart, B. Le Guennic, S. Golhen, O. Cador, L. Ouahab, Chem. Commun. 2013, 49, 11632-11634.
F. Pointillart, B. Le Guennic, O. Cador, O. Maury, L. Ouahab, Acc. Chem. Res. 2015, 48, 2834-2842.
F. Pointillart, J. Jung, R. Berraud-pache, B. Le Guennic, V. Dorcet, O. Cador, O. Maury, Y. Guyot, S. Decurtins, S.-X. Liu, L. Ouahab, Inorg. Chem. 2015, 54, 5384-5397.
M. Bendikov, F. Wudl, D. F. Perepichka, Chem. Rev. 2004, 104, 4891-4945.
C. Rovira, Chem. Rev. 2004, 104, 5289-5317.
L. S. Xie, M. Dincǎ, Isr. J. Chem. 2018, 58, 1119-1122.
J. Su, T. Hu, R. Murase, H. Wang, D. M. D. Alessandro, M. Kurmoo, J. Zuo, Inorg. Chem. 2019, 58, 3698-3706.
J. J. Baldoví, S. Cardona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño, A. Palii, Inorg. Chem. 2012, 51, 12565-12574.
Formula of MUV-5 a(Dy) is [Dy3(TTFTB)2(OOCCH3)(OCHN(CH3)2] having a coordinated DMF instead of H2O/OH, since these crystals were not properly washed and activated by heating.
C. F. Macrae, P. R. Edgington, P. McCabe, E. Pidcock, G. P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Crystallogr. 2006, 39, 453-457.
B. Chen, Z. P. Lv, C. F. Leong, Y. Zhao, D. M. D′alessandro, J. L. Zuo, Cryst. Growth Des. 2015, 15, 1861-1870.
B. Liu, B. Smit, Langmuir 2009, 25, 5918-5926.
T. J. Kistenmacher, T. E. Phillips, D. O. Cowan, Acta Crystallogr. Sect. B 1974, 30, 763-768.
V. Mukherjee, N. P. Singh, Spectrochim. Acta Part A 2014, 117, 315-322.
L. Sun, S. S. Park, D. Sheberla, M. Dincă, J. Am. Chem. Soc. 2016, 138, 14772-14782.
T. C. Umland, S. Allie, T. Kuhlmann, P. Coppens, J. Phys. Chem. 1988, 92, 6456-6460.
S. Vela, M. Souto, I. Ratera, C. Rovira, J. Veciana, J. Phys. Chem. A 2016, 120, 10297-10303.
Gaussian 09, Revision B.01, M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, G. A. Petersson, H. Nakatsuji, X. Li, M. Caricato, A. Marenich, J. Bloino, B. G. Janesko, R. Gomperts, B. Mennucci, H. P. Hratchian, J. V. Ortiz, A. F. Izmaylov, J. L. Sonnenberg, D. Williams-Young, F. Ding, F. Lipparini, F. Egidi, J. Goings, B. Peng, A. Petrone, T. Henderson, D. Ranasinghe, V. G. Zakrzewski, J. Gao, N. Rega, G. Zheng, W. Liang, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, K. Throssell, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, T. Keith, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, J. M. Millam, M. Klene, C. Adamo, R. Cammi, J. W. Ochterski, R. L. Martin, K. Morokuma, O. Farkas, J. B. Foresman, D. J. Fox, Gaussian, Inc., Wallingford CT, 2016.
A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652.
C. Adamo, V. Barone, J. Chem. Phys. 1999, 110, 6158-6170.
S. Abednatanzi, P. G. Derakhshandeh, H. Depauw, F.-X. Coudert, H. Vrielinck, P. Van Der Voort, K. Leus, Chem. Soc. Rev. 2019, 48, 2535-2565.
C. Strohhöfer, A. Polman, Opt. Mater. 2013, 21, 705-712.
K. A. White, D. A. Chengelis, K. A. Gogick, J. Stehman, N. L. Rosi, S. Petoud, J. Am. Chem. Soc. 2009, 131, 18069-18071.
F. Artizzu, F. Quochi, L. Marchiò, E. Sessini, M. Saba, A. Serpe, A. Mura, M. L. Mercuri, G. Bongiovanni, P. Deplano, J. Phys. Chem. Lett. 2013, 4, 3062-3066.
J. J. Baldoví, J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño, Dalton Trans. 2012, 41, 13705-13710.
J. J. Baldoví, S. Cardona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño, A. Palii, J. Comput. Chem. 2013, 34, 1961-1967.
L. Escalera-Moreno, J. J. Baldoví, A. Gaita-Ariño, E. Coronado, Chem. Sci. 2018, 9, 3265-3275.