Dynamic Role of Cluster Cocatalysts on Molecular Photoanodes for Water Oxidation.


Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
14 Aug 2019
Historique:
pubmed: 3 8 2019
medline: 3 8 2019
entrez: 3 8 2019
Statut: ppublish

Résumé

While loading of cocatalysts is one of the most widely investigated strategies to promote the efficiency of photoelectrodes, the understanding of their functionality remains controversial. We established new hybrid molecular photoanodes with cobalt-based molecular cubane cocatalysts on hematite as a model system. Photoelectrochemical and rate law analyses revealed an interesting functionality transition of the {Co(II)

Identifiants

pubmed: 31373808
doi: 10.1021/jacs.9b06100
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

12839-12848

Auteurs

Jingguo Li (J)

Department of Chemistry , University of Zurich , Winterthurerstrasse 190 , CH-8057 Zurich , Switzerland.

Wenchao Wan (W)

Department of Chemistry , University of Zurich , Winterthurerstrasse 190 , CH-8057 Zurich , Switzerland.

C A Triana (CA)

Department of Chemistry , University of Zurich , Winterthurerstrasse 190 , CH-8057 Zurich , Switzerland.

Zbynek Novotny (Z)

Department of Physics , University of Zurich , Winterthurerstrasse 190 , CH-8057 Zurich , Switzerland.

Jürg Osterwalder (J)

Department of Physics , University of Zurich , Winterthurerstrasse 190 , CH-8057 Zurich , Switzerland.

Rolf Erni (R)

Electron Microscopy Center , Empa, Swiss Federal Laboratories for Materials Science and Technology , CH-8600 Dübendorf , Switzerland.

Greta R Patzke (GR)

Department of Chemistry , University of Zurich , Winterthurerstrasse 190 , CH-8057 Zurich , Switzerland.

Classifications MeSH