Eudesmane-type sesquiterpene glycosides: sonneratiosides A-E and eudesmol β-D-glucopyranoside from the leaves of Sonneratia alba.


Journal

Journal of natural medicines
ISSN: 1861-0293
Titre abrégé: J Nat Med
Pays: Japan
ID NLM: 101518405

Informations de publication

Date de publication:
Jan 2020
Historique:
received: 04 06 2019
accepted: 01 08 2019
pubmed: 9 8 2019
medline: 17 3 2020
entrez: 9 8 2019
Statut: ppublish

Résumé

Five eudesmane-type sesquiterpene glycosides, named sonneratiosides A-E (1-5), were isolated from the leaves of Sonneratia alba (Lythraceae). The aglycone of sonneratioside A was identified as cryptomeridiol also known as proximadiol. X-ray crystallographic analysis of sonneratioside A confirmed its structure and its absolute stereochemistry. Eudesmol β-D-glucopyranoside (6) was also isolated from nature for the first time. The tyrosinase inhibitory activity was assayed for the new compounds together with seven known compounds. Among them, arbutin (12) showed the expected activity and luteolin 7-O-rutinoside (10) showed comparable activity to arbutin.

Identifiants

pubmed: 31392565
doi: 10.1007/s11418-019-01353-0
pii: 10.1007/s11418-019-01353-0
doi:

Substances chimiques

Glycosides 0
Naphthalenes 0
Sesquiterpenes 0
Sesquiterpenes, Eudesmane 0
cryptomeridiol 0
eudesmane 473-11-0
beta-eudesmol 473-15-4
Arbutin C5INA23HXF
Monophenol Monooxygenase EC 1.14.18.1
proximadiol Y2KBV9FZ9M

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

119-126

Références

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Auteurs

Kazuma Katsutani (K)

Graduate School of Biomedical and Health Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-ku, Hiroshima, 734-8553, Japan.

Sachiko Sugimoto (S)

Graduate School of Biomedical and Health Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-ku, Hiroshima, 734-8553, Japan.

Yoshi Yamano (Y)

Graduate School of Biomedical and Health Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-ku, Hiroshima, 734-8553, Japan.

Hideaki Otsuka (H)

Graduate School of Biomedical and Health Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-ku, Hiroshima, 734-8553, Japan. otsuka-h@yasuda-u.ac.jp.
Faculty of Pharmacy, Yasuda Women's University, 6-13-1 Yasuhigashi, Asaminami-ku, Hiroshima, 731-0153, Japan. otsuka-h@yasuda-u.ac.jp.

Katsuyoshi Matsunami (K)

Graduate School of Biomedical and Health Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-ku, Hiroshima, 734-8553, Japan. matunami@hiroshima-u.ac.jp.

Tsutomu Mizuta (T)

Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima, 739-8526, Japan.

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Classifications MeSH