Low-Resistance Molecular Wires Propagate Spin-Polarized Currents.


Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
18 09 2019
Historique:
pubmed: 15 8 2019
medline: 15 8 2019
entrez: 15 8 2019
Statut: ppublish

Résumé

Spin based properties, applications, and devices are typically related to inorganic ferromagnetic materials. The development of organic materials for spintronic applications has long been encumbered by its reliance on ferromagnetic electrodes for polarized spin injection. The discovery of the chirality-induced spin selectivity (CISS) effect, in which chiral organic molecules serve as spin filters, defines a marked departure from this paradigm because it exploits soft materials, operates at ambient temperature, and eliminates the need for a magnetic electrode. To date, the CISS effect has been explored exclusively in molecular insulators. Here we combine chiral molecules, which serve as spin filters, with molecular wires that despite not being chiral, function to preserve spin polarization. Self-assembled monolayers (SAMs) of right-handed helical (l-proline)

Identifiants

pubmed: 31411873
doi: 10.1021/jacs.9b06142
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

14707-14711

Auteurs

George Bullard (G)

Department of Chemistry , Duke University , Durham , North Carolina 27708 , United States.

Francesco Tassinari (F)

Department of Chemical and Biological Physics , Weizmann Institute of Science , Rehovot 76100 , Israel.

Chih-Hung Ko (CH)

Department of Chemistry , Duke University , Durham , North Carolina 27708 , United States.

Amit Kumar Mondal (AK)

Department of Chemical and Biological Physics , Weizmann Institute of Science , Rehovot 76100 , Israel.

Ruobing Wang (R)

Department of Chemistry , Duke University , Durham , North Carolina 27708 , United States.

Suryakant Mishra (S)

Department of Chemical and Biological Physics , Weizmann Institute of Science , Rehovot 76100 , Israel.

Ron Naaman (R)

Department of Chemical and Biological Physics , Weizmann Institute of Science , Rehovot 76100 , Israel.

Michael J Therien (MJ)

Department of Chemistry , Duke University , Durham , North Carolina 27708 , United States.

Classifications MeSH