Synthesis of Multifunctional Aryl(trifloxyalkenyl)iodonium Triflate Salts.
Journal
ACS omega
ISSN: 2470-1343
Titre abrégé: ACS Omega
Pays: United States
ID NLM: 101691658
Informations de publication
Date de publication:
31 May 2019
31 May 2019
Historique:
received:
15
03
2019
accepted:
26
03
2019
entrez:
29
8
2019
pubmed:
29
8
2019
medline:
29
8
2019
Statut:
epublish
Résumé
A convenient procedure for the synthesis of aryl(trifloxyalkenyl)iodonium triflate salts from commercially available (diacetoxyiodo)benzene, trimethylsilyl trifluoromethanesulfonate, and acetylenes under mild conditions was developed. The obtained multifunctional hypervalent vinyliodonium salts equipped with electrophilic and nucleophilic functions could serve as novel C2 synthons for organic transformations. The structure of the iodonium salts was identified by multidimensional NMR spectroscopy and X-ray crystallography.
Identifiants
pubmed: 31460007
doi: 10.1021/acsomega.9b00728
pmc: PMC6648789
doi:
Types de publication
Journal Article
Langues
eng
Pagination
9188-9197Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
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