Rotational Spectrum, Tunneling Motions, and Intramolecular Potential Barriers in Benzyl Mercaptan.
Journal
The journal of physical chemistry. A
ISSN: 1520-5215
Titre abrégé: J Phys Chem A
Pays: United States
ID NLM: 9890903
Informations de publication
Date de publication:
03 Oct 2019
03 Oct 2019
Historique:
pubmed:
6
9
2019
medline:
6
9
2019
entrez:
6
9
2019
Statut:
ppublish
Résumé
The rotational spectrum of benzyl mercaptan (parent and four isotopologues) has been assigned in a supersonic jet expansion using chirped-pulse Fourier transform microwave spectroscopy. The spectrum is characterized by torsional tunneling doublings, strongly perturbed by Coriolis interactions. The experimental rotational constants reveal that the sulfur atom is located above the ring plane in a
Identifiants
pubmed: 31487179
doi: 10.1021/acs.jpca.9b06921
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM