Long-Chain Polyorthoesters as Degradable Polyethylene Mimics.


Journal

Macromolecules
ISSN: 0024-9297
Titre abrégé: Macromolecules
Pays: United States
ID NLM: 0365316

Informations de publication

Date de publication:
26 Mar 2019
Historique:
received: 24 01 2019
revised: 27 02 2019
entrez: 10 9 2019
pubmed: 10 9 2019
medline: 10 9 2019
Statut: ppublish

Résumé

The persistence of commodity polymers makes the research for degradable alternatives with similar properties necessary. Degradable polyethylene mimics containing orthoester groups were synthesized by olefin metathesis polymerization for the first time. Ring-opening metathesis copolymerization (ROMP) of 1,5-cyclooctadiene with four different cyclic orthoester monomers gave linear copolymers with molecular weights up to 38000 g mol

Identifiants

pubmed: 31496544
doi: 10.1021/acs.macromol.9b00180
pmc: PMC6727593
doi:

Types de publication

Journal Article

Langues

eng

Pagination

2411-2420

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

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Auteurs

Tobias Haider (T)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.

Oleksandr Shyshov (O)

Institute of Organic Chemistry and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany.

Oksana Suraeva (O)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.

Ingo Lieberwirth (I)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.

Max von Delius (M)

Institute of Organic Chemistry and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, 89081 Ulm, Germany.

Frederik R Wurm (FR)

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.

Classifications MeSH