Acid p
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
09 10 2019
09 10 2019
Historique:
pubmed:
13
9
2019
medline:
13
9
2019
entrez:
13
9
2019
Statut:
ppublish
Résumé
Protons play essential roles in natural systems in controlling O-O bond cleavage of peroxoiron(III) species to give rise to the high-valent iron oxidants that carry out the desired transformations. Herein, we report kinetic and mechanistic evidence that acids can control the mode of O-O bond cleavage for a nonheme
Identifiants
pubmed: 31513741
doi: 10.1021/jacs.9b08442
doi:
Types de publication
Journal Article
Research Support, U.S. Gov't, Non-P.H.S.
Langues
eng
Sous-ensembles de citation
IM