Aromatic and Antiaromatic Pathways in Triphyrin(2.1.1) Annelated with Benzo[b]heterocycles.

acenes antiaromaticity aromaticity chirality triphyrin

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
05 Dec 2019
Historique:
received: 23 08 2019
pubmed: 20 9 2019
medline: 20 9 2019
entrez: 20 9 2019
Statut: ppublish

Résumé

Understanding of the aromatic properties and magnetically induced current densities of highly conjugated chromophores is important when designing molecules with strongly delocalized electronic structure. Linear extension of the triphyrin(2.1.1) skeleton with an annelated benzo[b]heterocycle fragment modifies the aromatic character by extending the electron delocalization pathway. Two-electron reduction leads to an antiaromatic triphyrin(2.1.1) ring and an aromatic benzo[b]heterocycle subunit. Current-density calculations provide detailed information about the observed pathways and their strengths.

Identifiants

pubmed: 31535404
doi: 10.1002/chem.201903863
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

15477-15482

Subventions

Organisme : Narodowe Centrum Nauki
ID : 2015/17/B/ST5/01437

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Krzysztof Bartkowski (K)

Department of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50383, Wrocław, Poland.

Maria Dimitrova (M)

Department of Chemistry, Faculty of Science, University of Helsinki, P.O. Box 55, 00014, Helsinki, Finland.

Piotr J Chmielewski (PJ)

Department of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50383, Wrocław, Poland.

Dage Sundholm (D)

Department of Chemistry, Faculty of Science, University of Helsinki, P.O. Box 55, 00014, Helsinki, Finland.

Miłosz Pawlicki (M)

Department of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50383, Wrocław, Poland.

Classifications MeSH