Trapping and Reactivity of a Molecular Aluminium Oxide Ion.
aluminium
aluminyl
oxide
reduction
small-molecule activation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
25 Nov 2019
25 Nov 2019
Historique:
received:
16
08
2019
pubmed:
25
9
2019
medline:
25
9
2019
entrez:
25
9
2019
Statut:
ppublish
Résumé
Aluminium oxides constitute an important class of inorganic compound that are widely exploited in the chemical industry as catalysts and catalyst supports. Due to the tendency for such systems to aggregate via Al-O-Al bridges, the synthesis of well-defined, soluble, molecular models for these materials is challenging. Here we show that reactions of the potassium aluminyl complex K
Identifiants
pubmed: 31550066
doi: 10.1002/anie.201910509
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
17265-17268Subventions
Organisme : Leverhulme Trust
ID : RP-2018-246
Organisme : Oxford SCG Centre of Excellence
Organisme : Academy of Finland
ID : 314794
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Références
F. K. Lutgens, E. J. Tarbuck in Essentials of geology, 7th ed., Prentice Hall 2000.
A. S. Marfunin in Advanced Mineralogy, Springer, Berlin, Heidelberg, 1994.
Selected examples include:
T. Saegusa, Y. Fujii, H. Fujii, J. Furukawa, Makromol. Chem. 1962, 55, 232-235;
S.-I. Ishida, J. Polym. Sci. 1962, 62, 1-14.
Selected examples include:
E. J. Vandenberg, J. Polym. Sci. A1 1969, 7, 525-567;
E. J. Vandenberg, Pure Appl. Chem. 1976, 48, 295-306;
Z. Florjańczyk, A. Plichta, M. Sobczak, Polymer 2006, 47, 1081-1090.
See: H. S. Zijlstra, S. Harder, Eur. J. Inorg. Chem. 2015, 19-43, and references therein.
J. H. Gary, J. H. Handwerk, M. J. Kaiser, D. Geddes in Petroleum Refining, Technology and Economics, 5th ed., CRC, Boca Raton, 2007.
A. J. Downs, H.-J Himmel in The Group 13 Metals Aluminium, Gallium, Indium and Thallium; Chemical Patterns and Peculiarities (Eds.: S. Aldridge, A. J. Downs), Wiley, Chichester, 2011.
The lattice energies of α- and γ-Al2O3 are of the order of 18 200 kJ mol−1: W. J. Borer, H. H. Günthard, Helv. Chim. Acta 1970, 53, 1043-1050.
M. R. Mason, J. M. Smith, S. G. Bott, A. R. Barron, J. Am. Chem. Soc. 1993, 115, 4971-4984.
G. Bai, H. W. Roesky, J. Li, M. Noltemeyer, H.-G. Schmidt, Angew. Chem. Int. Ed. 2003, 42, 5502-5506;
Angew. Chem. 2003, 115, 5660-5664.
R. J. Wehmschulte, P. P. Power, J. Am. Chem. Soc. 1997, 119, 8387-8388.
D. Neculai, H. W. Roesky, A. M. Neculai, J. Magull, B. Walfort, D. Stalke, Angew. Chem. Int. Ed. 2002, 41, 4294-4296;
Angew. Chem. 2002, 114, 4470-4472.
S. Singh, J. Chai, A. Pal, V. Jancik, H. W. Roesky, R. Herbst-Irmer, Chem. Commun. 2007, 4934-4936.
J. Hicks, P. Vasko, J. M. Goicoechea, S. Aldridge, Nature 2018, 557, 92-95. See also:
R. J. Schwamm, M. D. Anker, M. Lein, M. P. Coles, Angew. Chem. Int. Ed. 2019, 58, 1489-1493;
Angew. Chem. 2019, 131, 1503-1507;
M. D. Anker, M. P. Coles, Angew. Chem. Int. Ed. 2019, 58, 13452-13455.
J. Hicks, A. Mansikkamäki, P. Vasko, J. M. Goicoechea, S. Aldridge, Nat. Chem. 2019, 11, 237-241;
J. Hicks, P. Vasko, J. M. Goicoechea, S. Aldridge, J. Am. Chem. Soc. 2019, 141, 11000-11003.
Recent examples of carbonate formation from a silylene and CO2 include:
P. Jutzi, D. Eikenberg, A. Möhrke, B. Neumann, H.-G. Stammler, Organometallics 1996, 15, 753-759;
X. Liu, X.-Q. Xiao, Z. Xu, X. Yang, Z. Li, Z. Dong, C. Yan, G. Lai, M. Kira, Organometallics 2014, 33, 5434-5439;
Y. Wang, M. Chen, Y. Xie, P. Wei, H. F. Schaefer, G. H. Robinson, J. Am. Chem. Soc. 2015, 137, 8396-8399;
F. M. Mück, J. A. Baus, M. Nutz, C. Burschka, J. Poater, F. M. Bickelhaupt, R. Tacke, Chem. Eur. J. 2015, 21, 16665-16672;
A. Burchert, S. Yao, R. Müller, C. Schattenberg, Y. Xiong, M. Kaupp, M. Driess, Angew. Chem. Int. Ed. 2017, 56, 1894-1897;
Angew. Chem. 2017, 129, 1920-1923;
R. Rodriguez, I. Alvarado-Beltran, J. Saouli, N. Safferon-Merceron, A. Baceiredo, V. Branchadell, T. Kato, Angew. Chem. Int. Ed. 2018, 57, 2635-2638;
Angew. Chem. 2018, 130, 2665-2668;
D. Wendel, A. Porzelt, F. A. D. Herz, D. Sarkar, C. Jandl, S. Inoue, B. Rieger, J. Am. Chem. Soc. 2017, 139, 8134-8137;
D. Wendel, T. Szilvási, D. Henschel, P. J. Altmann, C. Jandl, S. Inoue, B. Rieger, Angew. Chem. Int. Ed. 2018, 57, 14575-14579;
Angew. Chem. 2018, 130, 14783-14787.
R. Lalrempuia, A. Stasch, C. Jones, Chem. Sci. 2013, 4, 4383-4388.
S. Bhaduri, B. F. G. Johnson, A. Pickard, P. R. Raithby, G. M. Sheldrick, C. I. Zuccaro, Chem. Commun. 1977, 354-355;
A. M. Wright, G. Wu, T. W. Hayton, J. Am. Chem. Soc. 2012, 134, 9930-9933.
See, for example
T. W. Hayton, W. B. Sharp, P. Legzdins, Chem. Rev. 2002, 102, 935-992;
P. Legzdins, G. B. Richter-Addo in Metal Nitrosyls, Oxford University Press, New York, 1992, and references therein.
As determined from a survey of the Cambridge Crystallographic Database, March 2019.
Recent examples of H2 activation by early transition metal imides include:
X. Han, L. Xiang, C. A. Lamsfus, W. Mao, E. Lu, L. Maron, X. Leng, Y. Chen, Chem. Eur. J. 2017, 23, 14728;
H. S. la Pierre, J. Arnold, F. D. Toste, Angew. Chem. Int. Ed. 2011, 50, 3900-3903;
Angew. Chem. 2011, 123, 3986-3989;
A. M. Geer, C. Tejel, J. A. López, M. A. Ciriano, Angew. Chem. Int. Ed. 2014, 53, 5614-5618;
Angew. Chem. 2014, 126, 5720-5724.
For C−H activation by early transition metal imides, see: P. T. Wolczanski, Organometallics 2018, 37, 505-516 (review).
D. W. Stephan, G. Erker, Angew. Chem. Int. Ed. 2015, 54, 6400-6441;
Angew. Chem. 2015, 127, 6498-6541.
CCDC 1943804, 1943805, 1943806, 1943807, and 1943808 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre.