Regioselective Oxidative Arylation of Fluorophenols.
arylated quinone
cross dehydrogenative coupling
fluorophenols
hypervalent iodine
regioselective arylation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
16 Dec 2019
16 Dec 2019
Historique:
received:
13
08
2019
revised:
24
09
2019
pubmed:
5
10
2019
medline:
5
10
2019
entrez:
5
10
2019
Statut:
ppublish
Résumé
A metal free and highly regioselective oxidative arylation reaction of fluorophenols is described. The relative position of the fluoride leaving group (i.e., ortho or para) controls the 1,2 or 1,4 nature of the arylated quinone product, lending versatility and generality to this oxidative, defluorinative, arylation concept.
Identifiants
pubmed: 31584740
doi: 10.1002/anie.201910352
pmc: PMC6916641
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
18530-18534Subventions
Organisme : ERC
ID : ERC project 716136: "2O2ACTIVATION"
Informations de copyright
© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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