Saturated N-Heterocyclic Carbene Based Thiele's Hydrocarbon with a Tetrafluorophenylene Linker.
C−F activation
Kekulé diradicaloids
density functional calculations
fluorine
saturated NHC
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
20 Dec 2019
20 Dec 2019
Historique:
revised:
06
10
2019
received:
25
09
2019
pubmed:
15
10
2019
medline:
15
10
2019
entrez:
15
10
2019
Statut:
ppublish
Résumé
The synthesis of a SIPr [1,3-bis(2,6-diisopropylphenyl)-imidazolin-2-ylidene] derived Kekulé diradicaloid with a tetrafluorophenylene spacer (3) has been described. Two synthetic routes have been reported to access 3. The cleavage of C-F bond of C
Identifiants
pubmed: 31609519
doi: 10.1002/chem.201904421
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
16533-16537Subventions
Organisme : Science and Engineering Research Board
ID : CRG/2018/000287
Organisme : Science and Engineering Research Board
ID : PDF/2017/000047
Organisme : DST-DFG
ID : INT/FRG/DFG/P-05/2017
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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