Oxidative Coupling of Benzylamines with Indoles in Aqueous Medium to Realize Bis-(Indolyl)Methanes Using a Water-Soluble Cobalt Catalyst and Air as the Oxidant.
aerobic oxidation
bis(indolyl)methane
cobalt catalyst
oxidative coupling
water soluble catalyst
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
02 Dec 2019
02 Dec 2019
Historique:
received:
18
09
2019
revised:
13
10
2019
pubmed:
15
10
2019
medline:
15
10
2019
entrez:
15
10
2019
Statut:
ppublish
Résumé
Oxidative coupling of benzylamines with indoles to bis-(indolyl)methanes (BIMs) was achieved using an inexpensive water-soluble cobalt complex, Co(bpb). The catalyst was found to be quite effective when air was used as the oxidant and water as solvent under mild reaction conditions. Aromatic amines were successfully converted to the corresponding BIMs with yields up to 85 %. We have successfully carried out a 1 gram scale reaction, and few pharmaceutically relevant compounds were also synthesised by this method in good yields. Control experiments have also been carried out to understand the possible reaction mechanism.
Identifiants
pubmed: 31609536
doi: 10.1002/asia.201901313
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4154-4159Subventions
Organisme : Council of Scientific and Industrial Research, India
ID : [01(2982)/19/EMR-II]
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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