Exploration of the Differences between Amine and Thiolate Addition to Acetylenedicarboxylates.


Journal

The Journal of organic chemistry
ISSN: 1520-6904
Titre abrégé: J Org Chem
Pays: United States
ID NLM: 2985193R

Informations de publication

Date de publication:
15 Nov 2019
Historique:
pubmed: 17 10 2019
medline: 17 10 2019
entrez: 17 10 2019
Statut: ppublish

Résumé

Nucleophilic addition of thiolates to diethyl acetylenedicarboxylate in chloroform at room temperature affords solely the meso dithioaddition product, whereas the addition of amines in ethanol gives only the corresponding (

Identifiants

pubmed: 31617716
doi: 10.1021/acs.joc.9b01392
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

14602-14610

Auteurs

Robyn L Crumbie (RL)

School of Science and Health , Western Sydney University , Locked Bag 1797 , Penrith, Sydney , NSW 2751 , Australia.

Gareth Chalmers (G)

School of Science and Health , Western Sydney University , Locked Bag 1797 , Penrith, Sydney , NSW 2751 , Australia.

Mohan Bhadbhade (M)

School of Chemistry , UNSW Australia , Sydney , NSW 2052 , Australia.

Renate Griffith (R)

School of Chemistry , UNSW Australia , Sydney , NSW 2052 , Australia.

Classifications MeSH