Dual self-assembly of supramolecular peptide nanotubes to provide stabilisation in water.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
17 10 2019
Historique:
received: 16 05 2019
accepted: 13 09 2019
entrez: 19 10 2019
pubmed: 19 10 2019
medline: 25 1 2020
Statut: epublish

Résumé

Self-assembling peptides have the ability to spontaneously aggregate into large ordered structures. The reversibility of the peptide hydrogen bonded supramolecular assembly make them tunable to a host of different applications, although it leaves them highly dynamic and prone to disassembly at the low concentration needed for biological applications. Here we demonstrate that a secondary hydrophobic interaction, near the peptide core, can stabilise the highly dynamic peptide bonds, without losing the vital solubility of the systems in aqueous conditions. This hierarchical self-assembly process can be used to stabilise a range of different β-sheet hydrogen bonded architectures.

Identifiants

pubmed: 31624265
doi: 10.1038/s41467-019-12586-8
pii: 10.1038/s41467-019-12586-8
pmc: PMC6797743
doi:

Substances chimiques

Macromolecular Substances 0
Nanotubes, Peptide 0
Peptides 0
Water 059QF0KO0R

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

4708

Subventions

Organisme : Medical Research Council
Pays : United Kingdom

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Auteurs

Julia Y Rho (JY)

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.

Henry Cox (H)

Biological Physics, School of Physics and Astronomy, University of Manchester, Manchester, M13 9PL, UK.

Edward D H Mansfield (EDH)

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.

Sean H Ellacott (SH)

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.

Raoul Peltier (R)

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.

Johannes C Brendel (JC)

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.

Matthias Hartlieb (M)

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.

Thomas A Waigh (TA)

Biological Physics, School of Physics and Astronomy, University of Manchester, Manchester, M13 9PL, UK.
Photon Science Institute, University of Manchester, Manchester, M13 9PL, UK.

Sébastien Perrier (S)

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK. S.perrier@warwick.ac.uk.
Faculty of Pharmacy and Pharmaceutical Sciences, Monash University, Parkville, VIC, 3052, Australia. S.perrier@warwick.ac.uk.
Warwick Medical School, University of Warwick, Coventry, CV4 7AL, UK. S.perrier@warwick.ac.uk.

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Classifications MeSH