Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)-Pheox complex.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
18 Nov 2019
18 Nov 2019
Historique:
pubmed:
23
10
2019
medline:
23
10
2019
entrez:
23
10
2019
Statut:
ppublish
Résumé
This work reports the first efficient enantioselective intramolecular Buchner reaction of diazoacetamides. The Ru(ii)-Pheox catalyst was shown to be highly efficient in this transformation in terms of both the regio- and enantioselectivity (up to 99% ee) giving the desired products in quantitative yield.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM