Extraction of the equilibrium pinning force on a contact line exerted from a wettability boundary of a solid surface through the connection between mechanical and thermodynamic routes.

By molecular dynamics (MD) simulations, we investigated the effects of chemical inhomogeniety of a wall surface on the equilibrium pinning behavior of a contact line (CL) of solid (S), liquid (L), and vapor (V) phases. We analyzed a quasi-two-dimensional LV-meniscus of Lennard-Jones fluid formed between two parallel flat solid walls, where the CL was located around the wetting boundary (WB) between lyophilic and lyophobic areas of the wall surface. Based on the relationship between the wall-tangential stress integral at the SL or SV interface and the corresponding thermodynamic work of adhesion W