Electronic structure of MAPbI


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
22 Oct 2019
Historique:
received: 17 06 2019
accepted: 28 08 2019
entrez: 24 10 2019
pubmed: 24 10 2019
medline: 24 10 2019
Statut: epublish

Résumé

Since their first appearance, organic-inorganic perovskite absorbers have been capturing the attention of the scientific community. While high efficiency devices highlight the importance of band level alignment, very little is known on the origin of the strong n-doping character observed in the perovskite. Here, by means of a highly accurate photoemission study, we shed light on the energy alignment in perovskite-based devices. Our results suggest that the interaction with the substrate may be the driver for the observed doping in the perovskite samples.

Identifiants

pubmed: 31641160
doi: 10.1038/s41598-019-50108-0
pii: 10.1038/s41598-019-50108-0
pmc: PMC6805902
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

15159

Subventions

Organisme : Ministero dell'Istruzione, dell'Università e della Ricerca
ID : RBAP11C58Y
Organisme : North Atlantic Treaty Organization
ID : Advanced Nanotechnologies For Multivariate Sensor Fabrication

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Auteurs

Marco Caputo (M)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy. marco.caputo@psi.ch.

Nicola Cefarin (N)

IOM-CNR Lab. TASC, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.
Dipartimento di Fisica - Università di Trieste, via Valerio Trieste, Trieste, Italy.

Andrea Radivo (A)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.
IOM-CNR Lab. TASC, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Nicola Demitri (N)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Lara Gigli (L)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Jasper R Plaisier (JR)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Mirco Panighel (M)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.
Dipartimento di Fisica - Università di Trieste, via Valerio Trieste, Trieste, Italy.

Giovanni Di Santo (G)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Sacha Moretti (S)

CNR - Institute of Atmospheric pollution Research - Sezione di Rende - c/o Polifunzionale - UNICAL 87036 Rende (CS), Rende, Italy.

Angelo Giglia (A)

IOM-CNR Lab. TASC, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Maurizio Polentarutti (M)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Filippo De Angelis (F)

Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), CNR-ISTM, Via Elce di Sotto 8, I-06123, Perugia, Italy.
CompuNet, Istituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy.

Edoardo Mosconi (E)

Computational Laboratory for Hybrid/Organic Photovoltaics (CLHYO), CNR-ISTM, Via Elce di Sotto 8, I-06123, Perugia, Italy.
CompuNet, Istituto Italiano di Tecnologia, Via Morego 30, 16163, Genova, Italy.

Paolo Umari (P)

IOM-CNR Lab. TASC, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.
Dipartimento di Fisica e Astronomia - Università di Padova, via Marzolo, 35131, Padova, Italy.

Massimo Tormen (M)

IOM-CNR Lab. TASC, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy.

Andrea Goldoni (A)

Elettra - Sincrotrone Trieste, s.s. 14 Km 163.5 in Area Science Park, Basovizza (Trieste) 34149, Trieste, Italy. andrea.goldoni@elettra.eu.

Classifications MeSH