Coating Distribution Analysis on Gas Diffusion Layers for Polymer Electrolyte Fuel Cells by Neutron and X-ray High-Resolution Tomography.


Journal

ACS omega
ISSN: 2470-1343
Titre abrégé: ACS Omega
Pays: United States
ID NLM: 101691658

Informations de publication

Date de publication:
22 Oct 2019
Historique:
received: 14 06 2019
accepted: 18 09 2019
entrez: 29 10 2019
pubmed: 28 10 2019
medline: 28 10 2019
Statut: epublish

Résumé

Coating load and distribution in gas diffusion layers (GDLs) for polymer electrolyte fuel cells (PEFCs) have a major influence on mass transport losses. To be able to optimize the coating distribution and get more accurate data about the influence of the coating on the PEFC performance, better characterization techniques are necessary. Common analysis techniques are limited to selected sections of the material, or they are not sensitive to small amounts of coating. We propose a new methodology to get a complete description of the coating distribution and the GDL structure by combining high-resolution X-ray tomography with high-resolution neutron tomography. Using an isotopic gadolinium staining method to enhance the neutron and X-ray absorption contrast, lower quantities of coating can be detected. The combination of both imaging techniques allows for a more detailed analysis of the coating distribution.

Identifiants

pubmed: 31656897
doi: 10.1021/acsomega.9b01763
pmc: PMC6811840
doi:

Types de publication

Journal Article

Langues

eng

Pagination

17236-17243

Informations de copyright

Copyright © 2019 American Chemical Society.

Déclaration de conflit d'intérêts

The authors declare no competing financial interest.

Références

Nat Methods. 2012 Jul;9(7):671-5
pubmed: 22930834
ACS Appl Mater Interfaces. 2015 Jul 15;7(27):15068-77
pubmed: 26098140
Opt Express. 2018 Jun 11;26(12):15769-15784
pubmed: 30114833
PLoS One. 2019 Jan 4;14(1):e0210300
pubmed: 30608985

Auteurs

Victoria Manzi-Orezzoli (V)

Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.

Adrian Mularczyk (A)

Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.

Pavel Trtik (P)

Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.

Jonathan Halter (J)

Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.

Jens Eller (J)

Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.

Thomas J Schmidt (TJ)

Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.
Laboratory of Physical Chemistry, Department of Chemistry & Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland.

Pierre Boillat (P)

Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.
Electrochemistry Laboratory and Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen, Switzerland.

Classifications MeSH