Nanometer-Scale Distribution of a Lubricant Modifier on Iron Films: A Frequency-Modulation Atomic Force Microscopy Study Combined with a Friction Test.

Liquid lubricants used in mechanical applications are low-vapor-pressure hydrocarbons modified with a small quantity of polar compounds. The polar modifiers adsorbed on the surface of sliding solids dominate the friction properties when the sliding surfaces are in close proximity. However, a few methods are available for the characterization of the adsorbed modifiers of a nanometer-scale thickness. In this study, we applied frequency-modulation atomic force microscopy to evaluate the vertical and lateral density distributions of the adsorbed modifier in a real lubricant, namely, poly-α-olefin (PAO) modified with an orthophosphoric acid oleyl ester. The liquid-induced force on the probing tip was mapped on a plane that was perpendicular to the lubricant-iron interface with a force sensitivity on the order of 10 pN. The PAO in the absence of the ester modifier was directly exposed to the film, which produced a few liquid layers parallel to the film surface with layer-to-layer distances of 0.6-0.7 nm. A monomolecular layer of the modifier was intermittently adsorbed with increasing ester concentration in the bulk lubricant, with complete coverage seen at 20 ppm. The C

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The authors declare no competing financial interest.