Water-Soluble Polymeric Carbon Nitride Colloidal Nanoparticles for Highly Selective Quasi-Homogeneous Photocatalysis.

carbon nitride chemoselectivity nanoparticles photocatalysis quasi-homogeneous catalysis

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
02 Jan 2020
Historique:
received: 18 10 2019
pubmed: 30 10 2019
medline: 30 10 2019
entrez: 30 10 2019
Statut: ppublish

Résumé

Heptazine-based polymeric carbon nitrides (PCN) are promising photocatalysts for light-driven redox transformations. However, their activity is hampered by low surface area resulting in low concentration of accessible active sites. Herein, we report a bottom-up preparation of PCN nanoparticles with a narrow size distribution (ca. 10±3 nm), which are fully soluble in water showing no gelation or precipitation over several months. They allow photocatalysis to be carried out under quasi-homogeneous conditions. The superior performance of water-soluble PCN, compared to conventional solid PCN, is shown in photocatalytic H

Identifiants

pubmed: 31659848
doi: 10.1002/anie.201913331
pmc: PMC6973021
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

487-495

Subventions

Organisme : Deutsche Forschungsgemeinschaft
ID : 364549901
Organisme : Deutsche Forschungsgemeinschaft
ID : BE 5102/3-1
Organisme : Deutsche Forschungsgemeinschaft
ID : TU 149/8-2
Organisme : Deutsche Forschungsgemeinschaft
ID : INST 275/257-1 FUGG
Organisme : MINECO
ID : MAT2016-78155-C2-1-R
Organisme : Gobierno del Principado de Asturias
ID : GRUPIN-ID2018-170
Organisme : CICECO-Aveiro Institute of Materials
ID : UID/CTM/50011/2019
Organisme : Ministério da Ciência, Tecnologia e Ensino Superior
ID : PTDC/QEQ-QAN/6373/2014
Organisme : University of Iceland Research Fund
Organisme : Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg
ID : INST 40/467-1 FUGG
Organisme : Alexander von Humboldt-Stiftung
Organisme : National NMR Network (PTNMR)
ID : Infrastructure Project Nº 022161

Informations de copyright

© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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Auteurs

Igor Krivtsov (I)

Department of Organic and Inorganic Chemistry, University of Oviedo-CINN, 33006, Oviedo, Spain.
Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081, Ulm, Germany.

Dariusz Mitoraj (D)

Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081, Ulm, Germany.

Christiane Adler (C)

Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081, Ulm, Germany.

Marina Ilkaeva (M)

CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193, Aveiro, Portugal.

Mariana Sardo (M)

CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193, Aveiro, Portugal.

Luís Mafra (L)

CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Campus Universitário de Santiago, 3810-193, Aveiro, Portugal.

Christof Neumann (C)

Institute of Physical Chemistry and Abbe Center of Photonics, Friedrich Schiller University Jena, Lessingstrasse 10, 07743, Jena, Germany.
Center for Energy and Environmental Chemistry Jena (CEEC Jena), Philosophenweg 7a, 07743, Jena, Germany.

Andrey Turchanin (A)

Institute of Physical Chemistry and Abbe Center of Photonics, Friedrich Schiller University Jena, Lessingstrasse 10, 07743, Jena, Germany.
Center for Energy and Environmental Chemistry Jena (CEEC Jena), Philosophenweg 7a, 07743, Jena, Germany.

Chunyu Li (C)

Institute of Physical Chemistry and Abbe Center of Photonics, Friedrich Schiller University Jena, Lessingstrasse 10, 07743, Jena, Germany.
Department Functional Interfaces, Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Strasse 9, 07745, Jena, Germany.

Benjamin Dietzek (B)

Institute of Physical Chemistry and Abbe Center of Photonics, Friedrich Schiller University Jena, Lessingstrasse 10, 07743, Jena, Germany.
Center for Energy and Environmental Chemistry Jena (CEEC Jena), Philosophenweg 7a, 07743, Jena, Germany.
Department Functional Interfaces, Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Strasse 9, 07745, Jena, Germany.

Robert Leiter (R)

Electron Microscopy of Materials Science, Central Facility for Electron Microscopy, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.

Johannes Biskupek (J)

Electron Microscopy of Materials Science, Central Facility for Electron Microscopy, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.

Ute Kaiser (U)

Electron Microscopy of Materials Science, Central Facility for Electron Microscopy, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.

Changbin Im (C)

Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081, Ulm, Germany.

Björn Kirchhoff (B)

Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081, Ulm, Germany.
Science Institute, University of Iceland, Dunhaga 5, 107, Reykjavík, Iceland.

Timo Jacob (T)

Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081, Ulm, Germany.
Helmholtz-Institute-Ulm (HIU), Helmholtzstrasse 11, 89081, Ulm, Germany.
Karlsruhe Institute of Technology (KIT), P.O. Box 3640, 76021, Karlsruhe, Germany.

Radim Beranek (R)

Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, 89081, Ulm, Germany.

Classifications MeSH