Coordination Polymer to Atomically Thin, Holey, Metal-Oxide Nanosheets for Tuning Band Alignment.
2D materials
band alignment
heterostructures
holey nanosheets
metal-based coordination polymers
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Dec 2019
Dec 2019
Historique:
received:
16
08
2019
revised:
08
10
2019
pubmed:
7
11
2019
medline:
7
11
2019
entrez:
7
11
2019
Statut:
ppublish
Résumé
Holey 2D metal oxides have shown great promise as functional materials for energy storage and catalysts. Despite impressive performance, their processing is challenged by the requirement of templates plus capping agents or high temperatures; these materials also exhibit excessive thicknesses and low yields. The present work reports a metal-based coordination polymer (MCP) strategy to synthesize polycrystalline, holey, metal oxide (MO) nanosheets with thicknesses as low as two-unit cells. The process involves rapid exfoliation of bulk-layered, MCPs (Ce-, Ti-, Zr-based) into atomically thin MCPs at room temperature, followed by transformation into holey 2D MOs upon the removal of organic linkers in aqueous solution. Further, this work represents an extra step for decorating the holey nanosheets using precursors of transition metals to engineer their band alignments, establishing a route to optimize their photocatalysis. The work introduces a simple, high-yield, room-temperature, and template-free approach to synthesize ultrathin holey nanosheets with high-level functionalities.
Identifiants
pubmed: 31693232
doi: 10.1002/adma.201905288
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e1905288Subventions
Organisme : Australian Research Council
ID : DP170104130
Organisme : Japan Society for the Promotion of Science
ID : 18F18064
Organisme : Generalitat de Catalunya
ID : 2017 SGR 327
Organisme : MINECO
ID : ENE2017-85087-C3
Organisme : MINECO
ID : SEV-2017-0706
Organisme : European Union's Horizon 2020 research and innovation programme
ID : 754510
Organisme : German Research Society
ID : HI 1867/1-1
Informations de copyright
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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