Stereospecific and Chemoselective Copper-Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates.
copper
nucleophilic substitution
silanes
stereospecificity
transmetalation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
20 Jan 2020
20 Jan 2020
Historique:
received:
30
09
2019
pubmed:
16
11
2019
medline:
16
11
2019
entrez:
16
11
2019
Statut:
ppublish
Résumé
A method for the synthesis of benzylsilanes starting from the corresponding ammonium triflates is reported. Silyl boronic esters are employed as silicon pronucleophiles, and the reaction is catalyzed by copper(I) salts. Enantioenriched benzylic ammonium salts react stereospecifically through an S
Identifiants
pubmed: 31730248
doi: 10.1002/anie.201912490
pmc: PMC7003868
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
1577-1580Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : Oe 249/15-1
Organisme : Einstein Stiftung Berlin
Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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