Cycloaddition Reactions of an Active Cyclic Phosphane/Borane Pair with Alkenes, Alkynes, and Carbon Dioxide.
boron
cyclic frustrated Lewis pair
cycloaddition
phosphorus
rearrangement
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
27 Jan 2020
27 Jan 2020
Historique:
received:
14
11
2019
pubmed:
19
11
2019
medline:
19
11
2019
entrez:
19
11
2019
Statut:
ppublish
Résumé
The active six-membered cyclo-FLP 6 undergoes a rapid P/B addition reaction to carbon dioxide. At elevated temperature, the resulting heterobicyclo[2.2.2]octane derived product 7 undergoes ring opening and equilibrates with the cyclotetramer (7)
Identifiants
pubmed: 31737944
doi: 10.1002/chem.201905171
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
1269-1273Subventions
Organisme : Deutsche Forschungsgemeinschaft
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Références
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CCDC 1951472 [(7)4], 1951473 (8), 1951474 (9), 1951475 (10), 1951476 (11), 1951477 (13), 1951478 (14), and 1951479 (16) contain the supplementary crystallographic data for this paper. These data are provided free of charge by The Cambridge Crystallographic Data Centre.