Shedding Light on the Interactions of Hydrocarbon Ester Substituents upon Formation of Dimeric Titanium(IV) Triscatecholates in DMSO Solution.
coordination compounds
helicate
solvent effects
thermodynamics
weak interactions
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
27 Jan 2020
27 Jan 2020
Historique:
received:
10
10
2019
pubmed:
19
11
2019
medline:
19
11
2019
entrez:
19
11
2019
Statut:
ppublish
Résumé
The dissociation of hierarchically formed dimeric triple lithium bridged triscatecholate titanium(IV) helicates with hydrocarbyl esters as side groups is systematically investigated in DMSO. Primary alkyl, alkenyl, alkynyl as well as benzyl esters are studied in order to minimize steric effects close to the helicate core. The
Identifiants
pubmed: 31737953
doi: 10.1002/chem.201904639
pmc: PMC7027801
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
1396-1405Subventions
Organisme : DFG
Organisme : Academy of Finland
ID : 298817
Informations de copyright
© 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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