Quantitative Structural Interpretation of Protein Crosslinks.


Journal

Structure (London, England : 1993)
ISSN: 1878-4186
Titre abrégé: Structure
Pays: United States
ID NLM: 101087697

Informations de publication

Date de publication:
07 01 2020
Historique:
received: 06 05 2019
revised: 11 09 2019
accepted: 28 10 2019
pubmed: 23 11 2019
medline: 2 10 2020
entrez: 23 11 2019
Statut: ppublish

Résumé

Chemical crosslinking, combined with mass spectrometry analysis, is a key source of information for characterizing the structure of large protein assemblies, in the context of molecular modeling. In most approaches, the interpretation is limited to simple spatial restraints, neglecting physico-chemical interactions between the crosslinker and the protein and their flexibility. Here we present a method, named NRGXL (new realistic grid for crosslinks), which models the flexibility of the crosslinker and the linked side-chains, by explicitly sampling many conformations. Also, the method can efficiently deal with overall protein dynamics. This method creates a physical model of the crosslinker and associated energy. A classifier based on it outperforms others, based on Euclidean distance or solvent-accessible distance and its efficiency makes it usable for validating 3D models from crosslinking data. NRGXL is freely available as a web server at: https://nrgxl.pasteur.fr.

Identifiants

pubmed: 31753619
pii: S0969-2126(19)30382-X
doi: 10.1016/j.str.2019.10.018
pii:
doi:

Substances chimiques

Cross-Linking Reagents 0
Proteins 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

75-82.e4

Informations de copyright

Copyright © 2019 Elsevier Ltd. All rights reserved.

Auteurs

Isaac Filella-Merce (I)

Structural Bioinformatics Unit, Department of Structural Biology and Chemistry, Institut Pasteur, CNRS UMR3528, C3BI, USR3756 Paris, France; Faculty of Health and Life Sciences, University Pompeu Fabra, Carrer del Doctor Aiguader 80, Barcelona 08003, Spain.

Benjamin Bardiaux (B)

Structural Bioinformatics Unit, Department of Structural Biology and Chemistry, Institut Pasteur, CNRS UMR3528, C3BI, USR3756 Paris, France.

Michael Nilges (M)

Structural Bioinformatics Unit, Department of Structural Biology and Chemistry, Institut Pasteur, CNRS UMR3528, C3BI, USR3756 Paris, France.

Guillaume Bouvier (G)

Structural Bioinformatics Unit, Department of Structural Biology and Chemistry, Institut Pasteur, CNRS UMR3528, C3BI, USR3756 Paris, France. Electronic address: guillaume.bouvier@pasteur.fr.

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Classifications MeSH