Renewable magnetic ion-selective colorimetric microsensors based on surface modified polystyrene beads.

Colorimetry Ion-selective optical sensor Magnetic nanoparticle Microspheres Polystyrene bead Potassium ion

Journal

Analytica chimica acta
ISSN: 1873-4324
Titre abrégé: Anal Chim Acta
Pays: Netherlands
ID NLM: 0370534

Informations de publication

Date de publication:
15 Jan 2020
Historique:
received: 16 05 2019
revised: 30 09 2019
accepted: 07 10 2019
entrez: 26 11 2019
pubmed: 26 11 2019
medline: 26 11 2019
Statut: ppublish

Résumé

Magnetic ion-selective colorimetric microspheres based on surface modification of polystyrene beads (0.8 μm diameter) are reported for the first time. The common components of ion-selective optode sensing (chromoionophore, ion-exchanger and ionophore) and magnetic nanoparticles are adsorbed onto the surface of the polystyrene particles using a simple mixed solvent method. The average diameter of the magnetic microspheres is evaluated by dynamic light scattering as 0.79 ± 0.06 μm. The reversible microsensors are circulated by flow and accumulated at a single spot by an applied magnet to become observable by digital camera. Hue signals are extracted from the recorded images to quantify the ratio of protonated and deprotonated form of the chromoionophore, which is the basis for optode response. The resulting magnetic microsensors respond to K

Identifiants

pubmed: 31761040
pii: S0003-2670(19)31207-3
doi: 10.1016/j.aca.2019.10.011
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

136-141

Informations de copyright

Copyright © 2019 Elsevier B.V. All rights reserved.

Auteurs

Sutasinee Apichai (S)

Department of Inorganic and Analytical Chemistry, University of Geneva, Quai Ernest-Ansermet 30, CH-1211, Geneva, Switzerland; Center of Excellence for Innovation in Analytical Science and Technology, Chiang Mai University, Chiang Mai, 50200, Thailand; Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand.

Lu Wang (L)

Department of Inorganic and Analytical Chemistry, University of Geneva, Quai Ernest-Ansermet 30, CH-1211, Geneva, Switzerland.

Kate Grudpan (K)

Center of Excellence for Innovation in Analytical Science and Technology, Chiang Mai University, Chiang Mai, 50200, Thailand; Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand.

Eric Bakker (E)

Department of Inorganic and Analytical Chemistry, University of Geneva, Quai Ernest-Ansermet 30, CH-1211, Geneva, Switzerland. Electronic address: eric.bakker@unige.ch.

Classifications MeSH