Photoswitchable single-walled carbon nanotubes for super-resolution microscopy in the near-infrared.


Journal

Science advances
ISSN: 2375-2548
Titre abrégé: Sci Adv
Pays: United States
ID NLM: 101653440

Informations de publication

Date de publication:
09 2019
Historique:
received: 23 02 2019
accepted: 27 08 2019
entrez: 5 12 2019
pubmed: 5 12 2019
medline: 5 12 2019
Statut: epublish

Résumé

The design of single-molecule photoswitchable emitters was the first milestone toward the advent of single-molecule localization microscopy, setting a new paradigm in the field of optical imaging. Several photoswitchable emitters have been developed, but they all fluoresce in the visible or far-red ranges, missing the desirable near-infrared window where biological tissues are most transparent. Moreover, photocontrol of individual emitters in the near-infrared would be highly desirable for elementary optical molecular switches or information storage elements since most communication data transfer protocols are established in this spectral range. Here, we introduce a type of hybrid nanomaterials consisting of single-wall carbon nanotubes covalently functionalized with photoswitching molecules that are used to control the intrinsic luminescence of the single nanotubes in the near-infrared (beyond 1 μm). Through the control of photoswitching, we demonstrate super-localization imaging of nanotubes unresolved by diffraction-limited microscopy.

Identifiants

pubmed: 31799400
doi: 10.1126/sciadv.aax1166
pii: aax1166
pmc: PMC6868679
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

eaax1166

Informations de copyright

Copyright © 2019 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).

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Auteurs

Antoine G Godin (AG)

Université de Bordeaux, Laboratoire Photonique Numérique et Nanosciences, UMR 5298, F-33400 Talence, France.
Institut d'Optique and CNRS, LP2N UMR 5298, F-33400 Talence, France.
Centre de recherche CERVO, Québec, Canada.
Department of Psychiatry and Neuroscience, Université Laval, Québec, Canada.

Antonio Setaro (A)

Department of Physics, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany.

Morgane Gandil (M)

Université de Bordeaux, Laboratoire Photonique Numérique et Nanosciences, UMR 5298, F-33400 Talence, France.
Institut d'Optique and CNRS, LP2N UMR 5298, F-33400 Talence, France.

Rainer Haag (R)

Institute of Organic Chemistry and Biochemistry, Freie Universität Berlin, Takustraße 3, 14195 Berlin, Germany.

Mohsen Adeli (M)

Institute of Organic Chemistry and Biochemistry, Freie Universität Berlin, Takustraße 3, 14195 Berlin, Germany.
Department of Chemistry, Faculty of Science, Lorestan University, Khorram Abad, Iran.

Stephanie Reich (S)

Department of Physics, Freie Universität Berlin, Arnimallee 14, 14195 Berlin, Germany.

Laurent Cognet (L)

Université de Bordeaux, Laboratoire Photonique Numérique et Nanosciences, UMR 5298, F-33400 Talence, France.
Institut d'Optique and CNRS, LP2N UMR 5298, F-33400 Talence, France.

Classifications MeSH