Cellulose-Based Microparticles for Magnetically Controlled Optical Modulation and Sensing.
cellulose nanocrystals
magneto-optical properties
microfluidics
microparticles
polarized light
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
01 2020
01 2020
Historique:
received:
01
08
2019
revised:
08
10
2019
pubmed:
6
12
2019
medline:
6
12
2019
entrez:
6
12
2019
Statut:
ppublish
Résumé
Responsive materials with birefringent optical properties have been exploited for the manipulation of light in several modern electronic devices. While electrical fields are often utilized to achieve optical modulation, magnetic stimuli may offer an enticing complementary approach for controlling and manipulating light remotely. Here, the synthesis and characterization of magnetically responsive birefringent microparticles with unusual magneto-optical properties are reported. These functional microparticles are prepared via a microfluidic emulsification process, in which water-based droplets are generated in a flow-focusing device and stretched into anisotropic shapes before conversion into particles via photopolymerization. Birefringence properties are achieved by aligning cellulose nanocrystals within the microparticles during droplet stretching, whereas magnetic responsiveness results from the addition of superparamagnetic nanoparticles to the initial droplet template. When suspended in a fluid, the microparticles can be controllably manipulated via an external magnetic field to result in unique magneto-optical coupling effects. Using a remotely actuated magnetic field coupled to a polarized optical microscope, these microparticles can be employed to convert magnetic into optical signals or to estimate the viscosity of the suspending fluid through magnetically driven microrheology.
Identifiants
pubmed: 31805220
doi: 10.1002/smll.201904251
doi:
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
e1904251Informations de copyright
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Références
W. M. Gibbons, P. J. Shannon, S.-T. Sun, B. J. Swetlin, Nature 1991, 351, 49.
P. S. Drzaic, J. Appl. Phys. 1986, 60, 2142.
R. C. Duarte, A. A. V. Flores, M. Stevens, Philos. Trans. R. Soc., B 2017, 372, 20160342.
L. F. Deravi, A. P. Magyar, S. P. Sheehy, G. R. R. Bell, L. M. Mäthger, S. L. Senft, T. J. Wardill, W. S. Lane, A. M. Kuzirian, R. T. Hanlon, E. L. Hu, K. K. Parker, J. R. Soc. Interface 2014, 11, 20130942.
T. J. Wardill, P. T. Gonzalez-Bellido, R. J. Crook, R. T. Hanlon, Proc. R. Soc. B 2012, 279, 4243.
P. C. M. Christianen, I. O. Shklyarevskiy, M. I. Boamfa, J. C. Maan, Phys. B 2004, 346-347, 255.
A. Böker, H. Elbs, H. Hänsel, A. Knoll, S. Ludwigs, H. Zettl, V. Urban, V. Abetz, A. H. E. Müller, G. Krausch, Phys. Rev. Lett. 2002, 89, 135502.
S. Lee, J. Y. Kim, S. Cheon, S. Kim, D. Kim, H. Ryu, RSC Adv. 2017, 7, 6988.
L. He, M. Wang, J. Ge, Y. Yin, Acc. Chem. Res. 2012, 45, 1431.
J. Ge, H. Lee, L. He, J. Kim, Z. Lu, H. Kim, J. Goebl, S. Kwon, Y. Yin, J. Am. Chem. Soc. 2009, 131, 15687.
Z. Zhao, R. Fang, Q. Rong, M. Liu, Adv. Mater. 2017, 29, 1703045.
T. Pullawan, A. N. Wilkinson, S. J. Eichhorn, Biomacromolecules 2012, 13, 2528.
R. Libanori, F. H. L. Münch, D. M. Montenegro, A. R. Studart, Compos. Sci. Technol. 2012, 72, 435.
H. Le Ferrand, F. Bouville, A. R. Studart, Soft Matter 2019, 15, 3886.
H. Le Ferrand, S. Bolisetty, A. F. Demirörs, R. Libanori, A. R. Studart, R. Mezzenga, Nat. Commun. 2016, 7, 12078.
M. Zeltner, R. N. Grass, A. Schaetz, S. B. Bubenhofer, N. A. Luechinger, W. J. Stark, J. Mater. Chem. 2012, 22, 12064.
S. B. Bubenhofer, E. K. Athanassiou, R. N. Grass, F. M. Koehler, M. Rossier, W. J. Stark, Nanotechnology 2009, 20, 485302.
R. Libanori, F. B. Reusch, R. M. Erb, A. R. Studart, Langmuir 2013, 29, 14674.
K.-H. Kim, J.-K. Song, NPG Asia Mater. 2009, 1, 29.
F. Ercole, T. P. Davis, R. A. Evans, Polym. Chem. 2010, 1, 37.
L. Cortese, L. Pattelli, F. Utel, S. Vignolini, M. Burresi, D. S. Wiersma, Adv. Opt. Mater. 2015, 3, 1337.
J. Teyssier, S. V. Saenko, D. van der Marel, M. C. Milinkovitch, Nat. Commun. 2015, 6, 6368.
L. M. Mäthger, E. J. Denton, N. J. Marshall, R. T. Hanlon, J. R. Soc. Interface 2009, 6, 149.
A. G. Dumanli, T. Savin, Chem. Soc. Rev. 2016, 45, 6698.
P. Kraft, C. Evangelista, M. Dacke, T. Labhart, M. V. Srinivasan, Philos. Trans. R. Soc., B 2011, 366, 703.
A. S. Utada, E. Lorenceau, D. R. Link, P. D. Kaplan, H. A. Stone, D. A. Weitz, Science 2005, 308, 537.
C. Ye, L. Kennedy, K. Shirk, U. M. Córdova-Figueroa, J. Youngblood, C. J. Martinez, Green Mater. 2015, 3, 25.
R. M. Parker, B. Frka-Petesic, G. Guidetti, G. Kamita, G. Consani, C. Abell, S. Vignolini, ACS Nano 2016, 10, 8443.
M. K. Hausmann, P. A. Rühs, G. Siqueira, J. Läuger, R. Libanori, T. Zimmermann, A. R. Studart, ACS Nano 2018, 12, 6926.
S. Schuerle, S. Erni, M. Flink, B. E. Kratochvil, B. J. Nelson, IEEE Trans. Magn. 2013, 49, 321.
S. Schuerle, I. A. Vizcarra, J. Moeller, M. S. Sakar, B. Özkale, A. M. Lindo, F. Mushtaq, I. Schoen, S. Pané, V. Vogel, B. J. Nelson, Sci. Rob. 2017, 2, eaah6094.
R. M. Erb, J. Segmehl, M. Charilaou, J. F. Löffler, A. R. Studart, Soft Matter 2012, 8, 7604.
R. M. Erb, L. Rafael, N. Rothfuchs, A. R. Studart, Science 2012, 335, 199.
S. Beck-Candanedo, M. Roman, D. G. Gray, Biomacromolecules 2005, 6, 1048.