A Small Cationic Organo-Copper Cluster as Thermally Robust Highly Photo- and Electroluminescent Material.

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
08 Jan 2020
Historique:
pubmed: 10 12 2019
medline: 10 12 2019
entrez: 10 12 2019
Statut: ppublish

Résumé

Organic light-emitting diodes (OLEDs) are revolutionizing display applications. In this aspect, luminescent complexes of precious metals such as iridium, platinum, or ruthenium still playing a significant role. Emissive compounds of earth-abundant copper with equivalent performance are desired for practical, large-scale applications such as solid-state lighting and displays. Copper(I)-based emitters are well-known to suffer from weak spin-orbit coupling and a high reorganization energy upon photoexcitation. Here we report a cationic organo-copper cluster [Cu

Identifiants

DOI: 10.1021/jacs.9b10829 PMID: 31814392
pubmed: 31814392
doi: 10.1021/jacs.9b10829
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

373-381

Auteurs

Marian Olaru (M)

Institut für Anorganische Chemie und Kristallographie , Universität Bremen , Leobener Straße 7 , 28359 Bremen , Germany.

Elena Rychagova (E)

G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , Tropinina, 49 , Nizhny Novgorod , 603950 , Russian Federation.

Sergey Ketkov (S)

G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , Tropinina, 49 , Nizhny Novgorod , 603950 , Russian Federation.
ORCID: 0000-0002-9603-2159

Yevhen Shynkarenko (Y)

Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience , ETH Zürich , Vladimir Prelog Weg 1 , CH-8093 Zürich , Switzerland.
Laboratory for Thin Films and Photovoltaics , Empa-Swiss Federal Laboratories for Materials Science and Technology , Überlandstrasse 129 , CH-8600 Dübendorf , Switzerland.
ORCID: 0000-0002-1587-1752

Sergii Yakunin (S)

Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience , ETH Zürich , Vladimir Prelog Weg 1 , CH-8093 Zürich , Switzerland.
Laboratory for Thin Films and Photovoltaics , Empa-Swiss Federal Laboratories for Materials Science and Technology , Überlandstrasse 129 , CH-8600 Dübendorf , Switzerland.
ORCID: 0000-0002-6409-0565

Maksym V Kovalenko (MV)

Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Bioscience , ETH Zürich , Vladimir Prelog Weg 1 , CH-8093 Zürich , Switzerland.
Laboratory for Thin Films and Photovoltaics , Empa-Swiss Federal Laboratories for Materials Science and Technology , Überlandstrasse 129 , CH-8600 Dübendorf , Switzerland.
ORCID: 0000-0002-6396-8938

Artem Yablonskiy (A)

Institute for Physics of Microstructures , Russian Academy of Sciences , 7 ul. Akademicheskaya , Nizhny Novgorod , 603950 , Russian Federation.

Boris Andreev (B)

Institute for Physics of Microstructures , Russian Academy of Sciences , 7 ul. Akademicheskaya , Nizhny Novgorod , 603950 , Russian Federation.

Florian Kleemiss (F)

Institut für Anorganische Chemie und Kristallographie , Universität Bremen , Leobener Straße 7 , 28359 Bremen , Germany.

Jens Beckmann (J)

Institut für Anorganische Chemie und Kristallographie , Universität Bremen , Leobener Straße 7 , 28359 Bremen , Germany.
ORCID: 0000-0002-8548-1821

Matthias Vogt (M)

Institut für Anorganische Chemie und Kristallographie , Universität Bremen , Leobener Straße 7 , 28359 Bremen , Germany.
ORCID: 0000-0002-2636-2531

Classifications MeSH