Chemically induced transformation of chemical vapour deposition grown bilayer graphene into fluorinated single-layer diamond.
Journal
Nature nanotechnology
ISSN: 1748-3395
Titre abrégé: Nat Nanotechnol
Pays: England
ID NLM: 101283273
Informations de publication
Date de publication:
Jan 2020
Jan 2020
Historique:
received:
04
07
2019
accepted:
26
10
2019
pubmed:
11
12
2019
medline:
11
12
2019
entrez:
11
12
2019
Statut:
ppublish
Résumé
Notwithstanding the numerous density functional studies on the chemically induced transformation of multilayer graphene into a diamond-like film carried out to date, a comprehensive convincing experimental proof of such a conversion is still lacking. We show that the fluorination of graphene sheets in Bernal (AB)-stacked bilayer graphene grown by chemical vapour deposition on a single-crystal CuNi(111) surface triggers the formation of interlayer carbon-carbon bonds, resulting in a fluorinated diamond monolayer ('F-diamane'). Induced by fluorine chemisorption, the phase transition from (AB)-stacked bilayer graphene to single-layer diamond was studied and verified by X-ray photoelectron, UV photoelectron, Raman, UV-Vis and electron energy loss spectroscopies, transmission electron microscopy and density functional theory calculations.
Identifiants
pubmed: 31819243
doi: 10.1038/s41565-019-0582-z
pii: 10.1038/s41565-019-0582-z
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
59-66Subventions
Organisme : Institute for Basic Science (IBS)
ID : IBS-R019-D1
Organisme : Institute for Basic Science (IBS)
ID : IBS-R019-D1
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