Crystal Transformation from the Incorporation of Coordinate Bonds into a Hydrogen-Bonded Network Yields Robust Free-Standing Supramolecular Membranes.

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
08 01 2020
Historique:
pubmed: 14 12 2019
medline: 14 12 2019
entrez: 14 12 2019
Statut: ppublish

Résumé

In this work, we report on the synthesis of a free-standing, macroscopic robust supramolecular membrane by introducing silver-nitrogen coordinate bonding into preorganized, supramolecular hydrogen-bonded cyanuric acid-melamine (CAM) crystals. With the assistance of ammonia, silver ions competitively replace two of the three hydrogen atoms from cyanuric acid resulting in the transformation from short CAM nanorods to long CAM-Ag nanofibers (length over 1000 μm), accompanied by tautomerization of cyanuric acid. The single crystal structure of the CAM-Ag nanofibers is solved in the space group

Identifiants

DOI: 10.1021/jacs.9b11336 PMID: 31833360
pubmed: 31833360
doi: 10.1021/jacs.9b11336
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

479-486

Auteurs

Peng Meng (P)

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.

Aidan Brock (A)

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.

Yanan Xu (Y)

Insitute for Future Environments, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.

Chenhui Han (C)

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.

Su Chen (S)

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.

Cheng Yan (C)

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.
ORCID: 0000-0002-4909-439X

John McMurtrie (J)

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.

Jingsan Xu (J)

School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty , Queensland University of Technology , Brisbane , QLD 4001 , Australia.
ORCID: 0000-0003-1172-3864

Classifications MeSH